![]() The work was supported by S3TEC, the Energy Frontier Research Center funded by the U.S. The research team also included Zhiwei Ding, Jiawei Zhou, and Professor Hong Liu at MIT, and Qingping Meng and Yimei Zhu at Brookhaven National Laboratory. I expect that this new formalism will lead to greatly improved understanding of the effects of dislocations on the electrical and thermal properties of materials. “The quantization developed in this paper goes a long way to solving these problems. Singh, a professor at the University of Missouri who also was not involved in this work. “Dislocations have profound effects on properties of materials, but until now the long-range nature of the strain field has prevented direct calculations of dislocation effects,” says David J. “Combining this with the quantum mechanical treatment of the dislon-electron interaction could lead to new strategies to optimize materials by using metallurgical approaches to engineer the structure, type, and location of dislocations within a material.” Li and his team have made “a breakthrough by being able to account for the long-range nature of the dislocation strain field, by treating it as a new quantum mechanical object called the dislon,” says Jeffery Snyder, a professor at Northwestern University, who was not connected to this work. He started from basic principles and derived a quantum description for it.” … I was very surprised when he came back with this new theory. “It’s a pretty complex problem: how dislocations affect these very important properties. “I didn’t put that much hope in it,” Chen said. Thermoelectric systems can also provide cooling, for cold-drink chests, for example.Ĭhen, who is the Carl Richard Soderberg Professor of Power Engineering, attributes the new findings to Li’s initiative. These are used for generating power from waste heat, or providing heaters for car seats. ![]() The findings could affect the search for better thermoelectric materials, which can convert heat to electricity. And while both of these approaches fail to explain behavior at the nanoscale, the new approach works well at such scales. It seems to resolve a number of issues, including a debate between two views known as the dynamic and static scattering approaches, showing they are simply two extreme cases within this new framework. The new theory, Li says, has a different starting point, as it is based on rigorous quantum field theory. There was a long debate about the nature of phonon scattering in dislocations.” “Before now, there were many empirical models, which need fitting parameters to be complete. “People have tried to learn how the dislocations change the material properties - the electrical and thermal properties,” Li says. Now, the MIT team has found a new mathematical approach to analyzing such systems, using a new quasiparticle they formulated called a “dislon,” which is a quantized version of a dislocation, which seems to resolve these longstanding mysteries. ![]() There have been two competing approaches to explaining phonon-dislocation interactions, Li explains, and a few other questions about them have remained unsolved. The findings are reported in the journal Nano Letters, in a paper co-authored by postdoc Mingda Li, Department of Mechanical Engineering head Professor Gang Chen, the late Institute Professor Emerita Mildred Dresselhaus, and five others.ĭislocations - which Li describes as “atomic irregularities in a regular crystal” - are very common defects in crystals, and they affect, for example, how heat dissipates through a silicon microchip or how well current flows through a silicon solar panel. But a precise understanding of the mechanism of the dislocation-phonon interaction has been elusive and controversial, which has slowed progress toward using dislocations to tailor the thermal properties of materials.Ī team at MIT has been able to learn important details about how those interactions work, which could inform future efforts to develop thermoelectric devices and other electronic systems. These defects have a strong effect on phonons, the modes of lattice vibration that play a role in the thermal and electrical properties of the crystals through which they travel. The effect is as if a knife had sliced through the crystal and then the pieces were stuck back together, askew from their original positions. ![]() New research offers insights into how crystal dislocations - a common type of defect in materials - can affect electrical and heat transport through crystals, at a microscopic, quantum mechanical level.ĭislocations in crystals are places where the orderly three-dimensional structure of a crystal lattice - whose arrangement of atoms repeats with exactly the same spacing - is disrupted. ![]()
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